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She was defeated by Venus Williams in straight sets.At the Australian Open Wozniacki defeated Gisela Dulko and 21st seed Alona Bondarenko on her way to the round of 16, where she lost to the eventual finalist and fourth-seeded Ana Ivanovic.Williams beat Wozniacki, ending a nine-match winning streak for Wozniacki.On 29 November Wozniacki was named ambassador for Danish Junior Tennis by the Culture Minister of Denmark at the time, Brian Mikkelsen.
She made her debut on the WTA Tour at Cincinnati's Western & Southern Financial Group Women's Open on 19 July 2005, losing to the top-seeded and eventual champion Patty Schnyder in the first round.
However, Wozniacki went on to win the Wimbledon girls' singles tournament, beating Slovak Magdaléna Rybáriková in the finals.
In August she reached another WTA Tour quarterfinal, this time at the Nordea Nordic Light Open in Stockholm.
In 2009, Wozniacki signed on to become an endorser for the line of tennis apparel designed by Stella Mc Cartney for Adidas.
She wore her first 'Adidas by Stella Mc Cartney' tennis dress at the 2009 US Open.
Months after Rory Mc Ilroy breaking up with her over the phone, Wozniacki and Washington linebacker Ryan Kerrigan attended a charity event together.